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Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern

Received: 24 March 2015     Accepted: 6 April 2015     Published: 18 April 2015
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Abstract

Polycyclic Aromatic Hydrocarbons (PAHs) toxicity and contamination of both terrestrial and aquatic ecosystem have been established PAHs are formed mainly as a result of incomplete combustion of organic materials during industrial and anthropogenic activities. Previous research has focused on various and many PAHs isomer pair ratio of variable physicochemical properties in source identification. The objective of this investigation was to determine the empirical validity of these isomer pairs (Ant/178, Flt/Flt+Pyr, B[a]a/228, I[123-cd]p/I[123-cd]p + B[ghi]p, Flu/Pyr, Phe/Ant, Chr/B([a]a and LPAHs/HPAHs) in source identification along sample station. In this way, 16 priority PAHs were determined in 10 sample stations in top and sub soil seasonally. After extraction, purification and quantification of PAHs was done using GC-FID. Reagents used are of chromatographic grade. Results showed that ratios are skewed either towards pyrolitic and/or petrogenic, and evaluation for petrogenic and pyrolitic source is different with isomer pair in each sample station even in areas were anthropogenic or industrial activity suggest otherwise. A suitable model/mechanism that shall take account of transformation products, type and extent of bacterial metabolism and environmental factors such as: pH, temperature, salinity, oxygen concentration, nutrients, light intensity, soil type as well as the presence of co-substrates and environmental matrix.

Published in International Journal of Environmental Monitoring and Analysis (Volume 3, Issue 3)
DOI 10.11648/j.ijema.20150303.11
Page(s) 111-117
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

PAHs Isomer Pair, Petrogenic, Pyrolitic, Variability, Sources Identification

References
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  • APA Style

    Emoyan Onoriode Onos, Agbaire Patience Odafe, Akporido Samuel Omorovie. (2015). Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern. International Journal of Environmental Monitoring and Analysis, 3(3), 111-117. https://doi.org/10.11648/j.ijema.20150303.11

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    ACS Style

    Emoyan Onoriode Onos; Agbaire Patience Odafe; Akporido Samuel Omorovie. Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern. Int. J. Environ. Monit. Anal. 2015, 3(3), 111-117. doi: 10.11648/j.ijema.20150303.11

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    AMA Style

    Emoyan Onoriode Onos, Agbaire Patience Odafe, Akporido Samuel Omorovie. Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern. Int J Environ Monit Anal. 2015;3(3):111-117. doi: 10.11648/j.ijema.20150303.11

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  • @article{10.11648/j.ijema.20150303.11,
      author = {Emoyan Onoriode Onos and Agbaire Patience Odafe and Akporido Samuel Omorovie},
      title = {Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern},
      journal = {International Journal of Environmental Monitoring and Analysis},
      volume = {3},
      number = {3},
      pages = {111-117},
      doi = {10.11648/j.ijema.20150303.11},
      url = {https://doi.org/10.11648/j.ijema.20150303.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijema.20150303.11},
      abstract = {Polycyclic Aromatic Hydrocarbons (PAHs) toxicity and contamination of both terrestrial and aquatic ecosystem have been established PAHs are formed mainly as a result of incomplete combustion of organic materials during industrial and anthropogenic activities. Previous research has focused on various and many PAHs isomer pair ratio of variable physicochemical properties in source identification. The objective of this investigation was to determine the empirical validity of these isomer pairs (Ant/178, Flt/Flt+Pyr, B[a]a/228, I[123-cd]p/I[123-cd]p + B[ghi]p, Flu/Pyr, Phe/Ant, Chr/B([a]a and LPAHs/HPAHs) in source identification along sample station. In this way, 16 priority PAHs were determined in 10 sample stations in top and sub soil seasonally. After extraction, purification and quantification of PAHs was done using GC-FID. Reagents used are of chromatographic grade. Results showed that ratios are skewed either towards pyrolitic and/or petrogenic, and evaluation for petrogenic and pyrolitic source is different with isomer pair in each sample station even in areas were anthropogenic or industrial activity suggest otherwise. A suitable model/mechanism that shall take account of transformation products, type and extent of bacterial metabolism and environmental factors such as: pH, temperature, salinity, oxygen concentration, nutrients, light intensity, soil type as well as the presence of co-substrates and environmental matrix.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Variability in Polycyclic Aromatic Hydrocarbons (PAHs) Isomer Pair Ratio: Source Identification Concern
    AU  - Emoyan Onoriode Onos
    AU  - Agbaire Patience Odafe
    AU  - Akporido Samuel Omorovie
    Y1  - 2015/04/18
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    DO  - 10.11648/j.ijema.20150303.11
    T2  - International Journal of Environmental Monitoring and Analysis
    JF  - International Journal of Environmental Monitoring and Analysis
    JO  - International Journal of Environmental Monitoring and Analysis
    SP  - 111
    EP  - 117
    PB  - Science Publishing Group
    SN  - 2328-7667
    UR  - https://doi.org/10.11648/j.ijema.20150303.11
    AB  - Polycyclic Aromatic Hydrocarbons (PAHs) toxicity and contamination of both terrestrial and aquatic ecosystem have been established PAHs are formed mainly as a result of incomplete combustion of organic materials during industrial and anthropogenic activities. Previous research has focused on various and many PAHs isomer pair ratio of variable physicochemical properties in source identification. The objective of this investigation was to determine the empirical validity of these isomer pairs (Ant/178, Flt/Flt+Pyr, B[a]a/228, I[123-cd]p/I[123-cd]p + B[ghi]p, Flu/Pyr, Phe/Ant, Chr/B([a]a and LPAHs/HPAHs) in source identification along sample station. In this way, 16 priority PAHs were determined in 10 sample stations in top and sub soil seasonally. After extraction, purification and quantification of PAHs was done using GC-FID. Reagents used are of chromatographic grade. Results showed that ratios are skewed either towards pyrolitic and/or petrogenic, and evaluation for petrogenic and pyrolitic source is different with isomer pair in each sample station even in areas were anthropogenic or industrial activity suggest otherwise. A suitable model/mechanism that shall take account of transformation products, type and extent of bacterial metabolism and environmental factors such as: pH, temperature, salinity, oxygen concentration, nutrients, light intensity, soil type as well as the presence of co-substrates and environmental matrix.
    VL  - 3
    IS  - 3
    ER  - 

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Author Information
  • Environmental and Food Chemistry Research Group, Department of Chemistry, Delta State University, P.M.B. 1 Abraka, Nigeria

  • Environmental and Food Chemistry Research Group, Department of Chemistry, Delta State University, P.M.B. 1 Abraka, Nigeria

  • Environmental and Food Chemistry Research Group, Department of Chemistry, Delta State University, P.M.B. 1 Abraka, Nigeria

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